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 Toner with wax component for developing electrostatic image

Details
Inventors: Onuma, Tsutomu; Matsunaga, Satoshi; Ohno, Manabu; Shimojo, Minoru;
Assignee: Canon Kabushiki Kaisha (Tokyo, JP)
Primary Examiner: Martin; Roland
Assistant Examiner:
Attorney, Agent or Firm: Fitzpatrick, Cella, Harper & Scinto

A toner for developing electrostatic images is prepared from a binder resin, a colorant or magnetic material, and a wax component. The toner is provided with improved low-temperature fixability anti-electrostatic offset characteristic, anti-blocking characteristic and anti-offset characteristic by controlling the thermal characteristic of the wax component so as to provide a DSC (differential scanning colorimeter) curve on temperature increase, showing a minimum onset temperature of heat absorption of at least 50.degree. C. and at least two heat absorption peaks including a largest and a second largest peaks, different from each other in peak temperature by at least 15.degree. C., wherein low-temperature heat absorption peak P.sub.1 of the two peaks shows a half-value width of at most 20.degree. C. and a higher-temperature heat absorption peak P.sub.2 shows a half-value width of at most 20.degree. C., and wherein the peak P.sub.1 shows a higher half-width temperature and the peak P.sub.2 shows a lower half-width temperature different form the higher half-width temperature of the peak P.sub.1 by at least 5.degree. C.

DETAILED DESCRIPTION An object of the present invention is to provide a toner for developing an electrostatic image having solved the above problems.
A more specific object of the invention is to provide a toner for developing an electrostatic image excellent in low-temperature fixability and anti-offset characteristic and providing a wide fixable temperature range.
Another object of the invention is to provide a toner for developing an electrostatic image excellent in anti-blocking characteristic and free from lowering in developing performance during a continuous image formation operation.
Another object of the present invention is to provide a toner for developing an electrostatic image containing little amount of a wax component isolated from toner particles and not causing a blotch on a developing sleeve due to an ununiform thickness of a toner coat layer on the sleeve.
Another object of the invention is to provide a toner for developing an electrostatic image excellent in anti-electrostatic offset characteristic.
A further object of the invention is to provide a toner for developing an electrostatic image free from melt-sticking or filming of a toner component onto a photosensitive member.
According to the present invention, there is provided a toner for developing an electrostatic image, comprising: a binder resin, a colorant or a magnetic material, and a wax component; wherein the wax component provides a DSC curve on temperature increase, as measured by a differential scanning calorimeter, showing a minimum onset temperature of heat absorption of at least 50.
degree.
C.
and at least two heat absorption peaks including a largest peak and a second largest peak of which a lower temperature peak P.
sub.
1 and a higher temperature peak P.
sub.
2 have a peak temperature difference therebetween of at least 15.
degree.
C.
, the lower temperature peak P.
sub.
1 shows a half-value width of at most 20.
degree.
C.
between a lower half-width temperature L.
sub.
1 P and a higher half-width temperature H



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