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 Impact-modified thermoplastics resin molding compositions and articles molded therefrom

Details
Inventors: Gallucci, Robert Russell; Hans, Paul Joseph; Janssen, Joseph Maria Henri; Mordecai, Woodie Daniel; Pixton, Matthew Robert;
Assignee: General Electric Company (Pittsfield, MA)
Primary Examiner: Mosley; Terressa
Assistant Examiner:
Attorney, Agent or Firm:

A method for making an impact modified thermoplastic resin composition includes combining an glycidyl ester impact modifier with a polycarbonate resin to form a glycidyl ester impact modifier-polycarbonate resin blend and then combining the glycidyl ester impact modifier-polycarbonate resin blend with a polyester resin to provide the impact modified thermoplastic resin composition. Articles molded from the impact modified thermoplastic resin composition made according to the method exhibit high impact resistance and improved surface appearance.

DETAILED DESCRIPTION OF THE INVENTION Polycarbonate Resin Aromatic polycarbonate resins suitable for use in the present invention, methods of making polycarbonate resins and the use of polycarbonate resins in thermoplastic molding compounds are well known in the art, see, generally, U.
S.
Pat.
Nos.
3,169,121, 4,487,896 and 5,411,999, the respective disclosures of which are each incorporated herein by reference.
Aromatic polycarbonate resins are, in general, prepared by reacting a dihydric phenol, e.
g.
, 2,2-bis-(4-hydroxyphenyl) propane ("bisphenol A"), 2,2-bis(3,5-dimethyl4-hydroxyphenyl)propane, bis(2-hydroxyphenyl) methane, 2,6-dihydroxy naphthalene, hydroquinone, 2,4'-dihydroxyphenyl sulfone and 4,4'-dihydroxy-3,3-dichlorophenyl ether, with a carbonate precursor, e.
g.
, carbonyl bromide and carbonyl chloride, a halogen formate, a bishaloformate of a dihydric phenol or a carbonate ester, e.
g.
, diphenyl carbonate, dichlorophenyl carbonate, dinaphthyl carbonate, phenyl tolyl carbonate and ditolyl carbonate.
In a preferred embodiment, the aromatic polycarbonate resin comprises one or more resins selected from linear aromatic polycarbonate resins, branched aromatic polycarbonate resins and poly(ester-carbonate) resins.
Suitable linear aromatic polycarbonates resins include, e.
g.
, bisphenol A polycarbonate resin.
Suitable branched aromatic polycarbonates are made, e.
g.
, by reacting a polyfunctional aromatic compound, e.
g.
, trimellitic anhydride, trimellitic acid, trimesic acid, trihydroxy phenyl ethane or trimellityl trichloride, with a dihydric phenol and a carbonate precursor to form a branching polymer.
Suitable poly(ester-carbonate) copolymers are made, e.
g.
, by reacting a difunctional carboxylic acid, terephthalic acid, 2,6-naphthalic acid, or a derivative of a difunctional carboxylic acid, e.
g.
, an acid chloride, with a dihydric phenol and a carbonate precursor.
In a preferred embodiment, the polycarbonate resin has an intrinsic viscosity of about 0.
3 to about 1.
5 deciliters per gram in methylene chloride at 25



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