Home | Links | Contact Us | More About Intellectual Property | Bookmark
Search patents:
Home Nonmetallic Processes Silicone-coating-for-unprimed-plastic-substrate-and-coated-articles

 Silicone coating for unprimed plastic substrate and coated articles

Details
Inventors: Ching, Ta-Yen;
Assignee: General Electric Company (Waterford, NY)
Primary Examiner: Lieberman; Allan
Assistant Examiner:
Attorney, Agent or Firm: Hedman, Casella, Costigan & Gibson

A silicone hardcoat composition for plastic substrates is provided in the form of an aqueous cohydrolyzate of chemically combined siloxy units, organosiloxy units and siloxy units having from 1-3 chemically combined UV stabilizing organic groups attached to silicon by carbon-silicon bonds. Thermoplastic substrates treated with such silicone hardcoat compositions are also provided.

DETAILED DESCRIPTION OF THE INVENTION The coating compositions of this invention are prepared by hydrolyzing a trialkoxysilane or a mixture of trialkoxysilanes of the formula RSi(OR').
sub.
3, wherein R is alkyl of from 1 to 3 carbons or aryl, such as phenyl, and R' is alkyl, in an aqueous dispersion of colloidal silica in thorough admixture with the functionalized ultraviolet light absorbing compound, and aging the mixture for a period of at least 2 hours at a temperature of at least 10.
degree.
C.
In the practice of the present invention, suitable aqueous colloidal silica dispersions generally have a particle size of from 5 to 150 millimicrons in diameter.
These silica dispersions are well known in the art and commercially available ones include, for example, those sold under the trademarks of Ludox (DuPont) and Nalcoag (NALCO Chemical Co.
).
Such colloidal silicas are available as both acidic and basic hydrosols.
For the purposes of this invention, basic colloidal silica sols are preferred.
However, acidic colloidal silicas are also contemplated.
In addition, it has been found that colloidal silicas having a low alkali content (e.
g.
, Na.
sub.
2 O) yield a more stable coating composition.
Thus, colloidal silica having an alkali content of less than 0.
35% (calculated as Na.
sub.
2 O) is preferred.
Moreoever, colloidal silicas having average particle size of from 10 to 30 millimicrons are also preferred.
A particularly preferred one for the purposes herein is known as Ludox LS, sold by DuPont Company.
In accordance with this invention, the aqueous colloidal silica dispersion is added to a solution of a small amount of alkyltriacetoxysilane or acetic acid in alkyltrialkoxysilane or aryltrialkoxysilane.
If desired, small amounts of dialkyl dialkoxysilane also can be utilized in the mixture.
The temperature of the reaction mixture is maintained at about 20.
degree.
C.
to about 40.
degree.
C.
and preferably below 25.
degree.
C.
It has been found that in about six to eight hours sufficient trialkoxysilane has reacted to reduce the initial two-phase liquid mixture to one liquid phase in which the now treated silica (i



Related patents
  Electrically conducting fiber and method of making same
OF THE INVENTION In the first stage of the process of the present invention, the acrylic or acrylic-series fibers, including modacrylic fibers, are heat-treated in a ...

0.034

Archive: All patents - Links

Copyright (c)2006 Eipa-patents.org - All rights reserved