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Home Optical Systems Curable-epoxy-resin-mixtures

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Details
Inventors: Haug, Theobald; Stockinger, Friedrich;
Assignee: Ciba Geigy Corporation (Ardsley, NY)
Primary Examiner:
Assistant Examiner:
Attorney, Agent or Firm:

Curable mixtures containing (a) epoxide compounds with on average more than one 1,2-epoxide group per molecule, (b) the condensates prepared from certain phenols, certain amines and aldehydes or ketones in an acid medium and, where relevant, (c) curing accelerators. The novel curable mixtures have a good storage stability and give shaped substances with outstanding resistance to chemicals.

DETAILED DESCRIPTION What is claimed is: 1.
A curable mixture comprising (a) an epoxide compound with on average more than one 1,2-epoxide group per molecule, (b) a condensate prepared in an acid medium from a phenol, amine and aldehyde or ketone, which is obtainable by reacting (1) a substituted monohydric phenol which is unsubstituted in the p-position and in one of the two o-positions or in both o-positions, an unsubstituted dihydric mononuclear phenol or an unsubstituted or substituted dihydric or polyhydric, dinuclear or polynuclear phenol which contains at least two reactive nucleus positions for reaction with an aldehyde or ketone, (2) a substituted aromatic monoamine which contains at least one reactive nucleus position for reaction with an aldehyde or ketone, an unsubstituted aromatic mononuclear or dinuclear diamine or a substituted aromatic mononuclear or dinuclear diamine which contains at least two reactive nucleus positions for reaction with an aldehyde or ketone, and (3) an aldehyde or ketone, with one another at a pH value of not more than 6, the molar ratio of phenol to amine to aldehyde or ketone in the reaction mixture being 1:1:1.
2 to 6:1:8, and 0.
9 to 1.
5 equivalents of active hydrogen atoms, based on the OH and NH.
sub.
2 group, being present in the curable mixture per 1 epoxide equivalent.
2.
A mixture according to claim 1 which contains an epoxide compound (a) with an aromatic group in the molecule.
3.
A mixture according to claim 1, which contains a polyglycidyl ether of a polyhydric phenol or an N-glycidyl compound of an aromatic amine as the epoxide compound (a).
4.
A mixture according to claim 1, which contains a condensate (b) in which reaction component (1) is a substituted monohydric phenol which is unsubstituted in the p-position and in one of the two o-positions or in the two o-positions, or is a substituted dihydric or polyhydric dinuclear or polynuclear phenol which contains at least two reactive nucleus positions for reaction with an aldehyde or ketone.
5



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