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 Process for making fluoropolymer finish composition

Details
Inventors: Tannenbaum, Harvey P.;
Assignee: E. I. Du Pont de Nemours and Company (Wilmington, DE)
Primary Examiner: Lusignan; Michael
Assistant Examiner:
Attorney, Agent or Firm: Tocker; Edwin

In the formation of a fluoropolymer non-stick layer on a substrate such as of cookware and bakeware, improved adhesion of the layer is obtained by co-grinding at least the polymer binder component with the pigment component. In an aqueous system, this co-grinding is carried out in water which contains a surfactant and the polymer binder is soluble in the water or water organic solvent mixture the resultant co-ground aqueous dispersion/solution is blended with aqueous dispersion of fluoropolymer to form the coating composition. Addition of inorganic filler film hardener to the co-grinding step also improves the scratch resistance of the of the non-stick layer.

DETAILED DESCRIPTION Aqueous dispersions of fluoropolymer are commercially available from fluoropolymer manufacturers.
The fluoropolymer is present in the dispersion in very small particle size, e.
g.
about 0.
2 micrometer and, and the particles remain dispersed via a surfactant being present in the dispersion without causing coagulation.
The stability of the dispersion is such that it can be stirred for the purpose of blending other ingredients into the dispersion.
Examples of fluoropolymers include polytetrafluoroethylene (PTFE), which is not melt fabricable, and copolymers of tetrafluoroethylene (TFE) with at least on other monomer in a sufficient amount that makes the resultant copolymer melt-fabricable.
Examples of PTFE include the homopolymer and modified PTFE, which contains a small amount of co monomer such as hexafluoropropylene (HFP) or perfluoro(alkyl vinyl) ether (PAVE), wherein the alkyl group contains from 1 to 5 carbon atoms.
Examples of melt fabricable fluoropolymers include copolymers of TFE with one or more of perfluoroolefins, such as 1tFP, and PAVE, such as the copolymer of tetrafluoroethylene with perfluoro(propyl vinyl) ether (PFA).
The fluoropolymer component: of the finish composition can consist of a single fluoropolymer or a mixture thereof in the aqueous dispersion.
The mixture can be made by blending aqueous dispersions of individual fluoropolymers.
The PTFE described above will usually have a melt viscosity of at least 1.
times.
10.
sup.
9 Pa.
s.
A lower melt viscosity PTFE is available, called PTFE micropowder, having a melt viscosity of 1.
times.
10.
sup.
2 to 1.
times.
10.
sup.
7 Pa.
s, can also be used in the present invention.
it can be obtained by aqueous dispersion polymerization, in which case it is in a form which is convenient for use in the aqueous dispersion embodiment of the present invention.
Another method of obtaining the micropowder is irradiation of the higher melt viscosity PTFE.
This micropowder is in convenient form for use in the organic solvent embodiment of the present invention



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