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 Method for forming a direct positive image

Details
Inventors: Inoue, Noriyuki; Hirano, Shigeo; Kojima, Tetsuro; Yamamoto, Mitsura; Nagaoka, Satoshi;
Assignee: Fuji Photo Film Co. Ltd. (Kanagawa, JP)
Primary Examiner: Michl; Paul R.
Assistant Examiner: Chea; Thorl
Attorney, Agent or Firm: Sughrue, Mion, Zinn, Macpeak & Seas

A method for forming a direct positive image comprising the steps of: (a) imagewise exposing a photographic light-sensitive material composed of a support having thereon at least one unprefogged internal latent image type silver halide light-sensitive emulsion layer; and (b) developing the exposed photographic light-sensitive material to form a direct positive image in the presence of at least one nucleating agent represented by formula (N-I); ##STR1## wherein Z.sup.1 represents nonmetal atomic group necessary for forming a 5-membered or 6-membered heterocyclic ring, a 5-membered or 6-membered heterocyclic ring fused with an aromatic ring, or a 5-membered or 6-member heterocyclic ring fused with another heterocyclic ring; R.sup.1 represents an aliphatic group; X represents ##STR2## Q represents a nonmetallic atomic group necessary for forming a 4-membered to 12-membered nonaromatic hydrocarbon ring or a 4-membered to 12-membered nonaromatic heterocyclic ring; provided that at least one of R.sup.1, Z.sup.1 and Q is substituted with an alkynyl group; Y represents a counter ion required for charge balance; and n is a number required for charge balance; or Z.sup.1 contains a heterocyclic quaternary ammonium salt completed by said Z.sup.1 via a linkage group.

DETAILED DESCRIPTION OF THE INVENTION The nucleating agent represented by the foregoing general formula (N-I) is illustrated in detail below.
Specific examples of a heterocyclic ring completed by Z.
sup.
1 include quinolinium, benzimidazolium, pyridinium, thiazolium, selenazolium, imidazolium, tetrazolium, indolenium, pyrrolinium, acridinium, phenanthridinium, isoquinolinium and naphthopyridinium nuclei.
Z.
sup.
1 may be substituted by a substituent group, such as an alkyl group, an alkenyl group, an aralkyl group, an aryl group, an alkynyl group, a hydroxyl group, an alkoxy group, an aryloxy group, a halogen atom, an amino group, an alkylthio group, an arylthio group, an acyloxy group, an acylamino group, an aliphatic and aromatic sulfonyl group, an aliphatic and aromatic sulfonyloxy group, an aliphatic and aromatic sulfonylamino group, a carboxyl group, an acyl group, a carbamoyl group, a sulfamoyl group, a sulfo group, a cyano group, a ureido group, a urethane group (including an alkoxyamido group and a carbamoyloxy group), a carboxylate group (having a structure of ROCOO--), a hydrazino group, a hydrazono group, and an imino group.
As for the substituent groups by which Z.
sup.
1 may be substituted, at least one substituent is chosen from those cited above.
When Z.
sup.
1 has two or more of groups as substituents, these groups may be the same or different.
The substituent groups as set forth above may further be substituted by any of them.
The carbon number in an aryl moiety or an aralkyl moiety in the substituents is preferably from 6 to 20 and in an alkyl moiety in the substituents is preferably from 1 to 18.
Further, Z.
sup.
1 may contain a heterocyclic quaternary ammonium salt completed by Z.
sup.
1 via an appropriate linkage group L.
sup.
1.
Two Z.
sup.
1 groups may be the same or different.
In this case, the nucleating agent assumes, for example, a structure of a bis-compound.
Preferred examples of the heterocyclic nucleus completed by Z.
sup.
1 include quinolinium, benzimidazolium, pyridinium, acridinium, phenanthridinium, naphthopyridinium and isoquinolinium nuclei



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