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Light-sensitive mixture and copying material prepared therefrom, and process for the preparation of a printing form from the copying material
| Details |
Inventors: Stahlhofen, Paul;
Assignee: Hoechst Aktiengesellschaft (Frankfurt am Main, DE)
Primary Examiner: Brown; J. Travis
Assistant Examiner:
Attorney, Agent or Firm: Schwartz, Jeffery, Schwaab, Mack, Blumenthal & Koch
A light-sensitive mixture is disclosed which contains a water-insoluble, aqueous-alkali-soluble binder, a light-sensitive o- or p-quinone-diazide or a mixture of (a) a compound which generates or splits off an acid on exposure to light and (b) a compound having at least one C--O--C group which can be cleaved by acid, and a phenol compound having 1 to 3 benzene nuclei which are mutually linked by single bonds, carbonyl groups, ether groups, thioether groups or optionally substituted methylene groups, and having at least one phenolic hydroxyl group and at least two substituents of the formula --CH.sub.2 OR, in which R is hydrogen or a lower alkyl or acyl group. The mixture is used for the preparation of light-sensitive copying material, preferably for the preparation of planographic printing forms. The addition of the phenolic compound has the effect that the developed printing forms can be baked at lower temperatures than hitherto in order to extend the printing run. |
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DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS The invention begins with a light-sensitive mixture containing a water-insoluble binder, which is soluble in aqueous-alkaline solutions, a light-sensitive o- or p-quinone-diazide or a mixture of (a) a compound which generates or splits off an acid on exposure to light and (b) a compound having at least one C--O--C group which can be cleaved by acid, and a phenol derivative. In the mixture according to the invention, the phenol derivative is a compound having 1 to 3 benzene nuclei which are mutually linked by single bonds, carbonyl groups, ether groups, thioether groups or optionally substituted methylene groups, and having at least one phenolic hydroxyl group and at least two substituents of the formula --CH. sub. 2 OR, in which R is a hydrogen atom, or a lower alkyl or acyl group. Furthermore, according to the inventon, a light-sensitive copying material is provided which is composed of a support and a light-sensitive layer constituted by the mixture defined above. Moreover, according to the invention, a process for the preparation of a printing form is provided, wherein a light-sensitive copying material composed of a support and a light-sensitive layer containing a water-insoluble binder, which is soluble in aqueous-alkaline solutions, a light-sensitive o- or p- quinone-diazide or a mixture of (a) a compound which generates or splits off an acid on exposure to the light and (b) a compound having at least one C--O--C group which can be cleaved by acid, and a phenol derivative, is exposed imagewise, the non-image areas of the layer are washed out with an aqueous-alkaline developer solution and the material is then heated to an elevated temperature in order to harden the image layer. This process utilizes the light-sensitive copying material defined above. The phenol derivatives contained in the mixture according to the invention can, for example, correspond to one of the general formulae I and II ##STR1## in which R is a hydrogen atom, a lower alkyl group or a lower acyl group, R' is an alkyl, alkoxy, cycloalkyl, aryl, aryloxy, acyl or aralkyl group or a halogen atom, X is a single bond or one of the groups S, O, CO or CR
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