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 6-tetrahydrofurfurylaminofluoran compound useful as a color former

Details
Inventors: Sensui, Hideyuki; Suzuka, Susumu; Gonda, Michihiro; Kikkawa, Katsumasa;
Assignee: Hodogaya Chemical Co., Ltd. (Tokyo, JP)
Primary Examiner:
Assistant Examiner:
Attorney, Agent or Firm:

A novel 6-tetrahydrofurfurylaminofluoran compound useful as a color former (precursory colorant) for a heat-sensitive recording sheet is of the formula (I): ##STR1## wherein R.sub.1 is H, C.sub.1-8 alkyl, tetrahydrofurfuryl, phenyl, alkyl(C.sub.1-5)phenyl, or C.sub.3-8 cyclic alkyl, R.sub.2 is H, Cl, F, C.sub.1-5 alkyl, C.sub.1-5 alkoxy, C.sub.2-10 alkoxyalkyl, phenyl or benzyl, and R.sub.3 is H, Cl, F, C.sub.1-5 alkyl and C.sub.2-7 acryl.

DETAILED DESCRIPTION We claim: 1.
A 6-tetrahydrofurfurylaminofluoran compound of the formula (I): R1 ? ? ##STR24## wherein R.
sub.
1 represents a member selected from the group consisting of a hydrogen atom, alkyl radicals having 1 to 8 carbon atoms, a tetrahydrofurfuryl radical, a phenyl radical, an alkylphenyl radical in which the alkyl group has 1 to 5 carbon atoms, and cyclic alkyl radicals having 3 to 8 carbon atoms; R.
sub.
2 represents a member selected from the group consisting of a hydrogen atom, chlorine atom, fluorine atom, alkyl radicals having 1 to 5 carbon atoms, alkoxy radicals having 1 to 5 carbon atoms, alkoxyalkyl radicals having 2 to 10 carbon atoms, a phenyl radical, and a benzyl radical; and R.
sub.
3 represents a hydrogen atom, chlorine atom, fluorine atom, alkyl radicals having 1 to 5 carbon atoms, and acyl radicals having 2 to 7 carbon atoms.
2.
The fluoran compound as claimed in claim 1, selected from 2-anilino-3-methyl-6-N-methyl-N-tetrahydrofurfurylaminofluoran, 2-anilino-3-methyl-6-N-ethyl-N-tetrahydrofurfurylaminofluoran, 2-anilino-3-chloro-6-N-methyl-N-tetrahydrofurfurylaminofluoran, 2-(2-chloroanilino)-6-N-methyl-N-tetrahydrofurfurylaminofluoran, 2-(2-chloroanilino)-6-N,N-ditetrahydrofurfurylaminofluoran, 2-anilino-3-methyl-6-N,N-ditetrahydrofurfurylaminofluoran, 2-anilino-3-methyl-6-N-isoamyl-N-tetrahydrofurfurylaminofluoran, 2-anilino-3-methyl-6-N-butyl-N-tetrahydrofurfurylaminofluoran, 2-anilino-3-ethoxyethyl-6-N-methyl-N-tetrahydrofurfurylaminofluoran, 2-anilino-3-methyl-N-p-tolyl-N-tetrahydrofurfurylaminofluoran, 2-anilino-3-methyl-6-N-cyclohexyl-N-tetrahydrofurfurylaminofluoran, 2-anilino-3-methyl-N-tetrahydrofurfurylaminofluoran, 2-anilino-3-phenyl-6-N-methyl-N-tetrahydrofurfurylaminofluoran, 2-anilino-3-phenyl-6-N-ethyl-N-tetrahydrofurfurylaminofluoran, 2-anilino-3-benzyl-6-N-methyl-N-tetrahydrofurfurylaminofluoran, 2-anilino-3-methoxy-6-N-methyl-N-tetrahydrofurfurylaminofluoran, 2-p-toluidino-3-methyl-6-N-methyl-N-tetrahydrofurfurylaminofluoran, 2-(p-benzoyl-phenylamino)-3-ethyl-6-N-methyl-N-tetrahydrofurfurylaminofluo ran, 2-(2-fluoroanilino)-6-N-methyl-N-tetrahydrofurfurylaminofluoran, and 2-anilino-3-benzyl-6-N,N-ditetrahydrofurfurylaminofluoran



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