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Home TV Signal Heat-development-of-silver-halide-element-with-redox-dye-releaser-and-stabilizer

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 Heat development of silver halide element with redox dye releaser and stabilizer

Details
Inventors: Sakaguchi, Yukihiko; Aono, Toshiaki; Fujita, Shinsaku;
Assignee: Fuji Photo Film Co., Ltd. (Kanagawa, JP)
Primary Examiner:
Assistant Examiner:
Attorney, Agent or Firm:

A process for forming an image is described, comprising heating a light-sensitive material in a substantially water-free condition to form a mobile dye in an image pattern, said material having a support bearing thereon light-sensitive silver halide, a binder, and a dye-releasing redox compound capable of imagewise reducing the silver halide and releasing a hydrophilic dye on reaction with said silver halide when heated, after or simultaneously with imagewise exposure, in the presence of a compound having a melting point below 60.degree. C. represented by formula (A) ##STR1## wherein p is an integer of 1 to 5 and q is an integer of 1 to 4, provided that p+q is 6 or less; R represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group, an alkoxy group, an aryloxy group, an aralkyl group, an acyl group, an acylamino group, an alkylsulfonylamino group, an alkoxyalkyl group, an aryloxyalkyl group, an acyloxy group, an acyloxyalkyl group, a carbamoyl group, an N-substituted carbamoyl group, a ureido group, an N-substituted ureido group, an alkylamino group, a dialkylamino group, an arylamino group, a halogen atom, a hydroxy group, a carboxy group, a nitro group, a cyano group, an alkyoxycarbonyl group, an aryloxycarbonyl group, or a cycloalkyloxycarbonyl group; and R.sup.1 represents an alkyl group, an alkenyl group, a cycloalkyl group, an alkenyl group, a cycloalkyl group or an aryl group. Also, a heat developable light-sensitive material is disclosed.

DETAILED DESCRIPTION OF THE INVENTION The alkyl, cycloalkyl and aryl groups represented by R or the alkyl, cycloalkyl and aryl moieties of the groups represented by R may be substituted with a halogen atom, a hydroxy group, an alkoxy group, a cyano group, an aryloxy group, an alkyl group, an alkoxycarbonyl group or an aryloxycarbonyl group.
When p is 2 or more, the R's may be the same or different.
The alkyl, cycloalkyl and aryl groups represented by R.
sup.
1 may be substituted with a halogen atom, a hydroxy group, an alkoxy group, a cyano group, an aryloxy group, an alkyl group or an alkoxycarbonyl group.
When q is 2 or more, the R.
sup.
1 's may be the same or different.
When R represents a group containing one or more carbon atoms, the total number of the carbon atom(s) of the group inclusive of the substituent(s), if any, is preferably from 1 to 40, and more preferably from 1 to 20 carbon atoms.
Preferred examples of R include alkyl groups (for example, a methyl group, an ethyl group, a butyl group, an isoheptyl group, an octyl group, a tetradecyl group, etc.
), alkoxy groups (for example, a methoxy group, an ethoxy group, a butoxy group, etc.
), halogen atoms (for example, chlorine, bromine, fluorine, etc.
), and a hydrogen atom.
Of these, a hydrogen atom is particularly preferred.
It is preferred for the alkyl, alkenyl, cycloalkyl or aryl group represented by R.
sup.
1 to have 60 or less carbon atoms inclusive of the substituent(s) thereof, if any.
In formula (A), R.
sup.
1 is preferably an alkyl group having from 1 to 40, and more preferably from 1 to 20 carbon atoms, a cycloalkylalkyl group having from 6 to 46, and more preferably from 6 to 26 carbon atoms, an alkenyl group having from 2 to 40, and more preferably 2 to 20 carbon atoms, an alkoxyalkyl group having from 3 to 60, and more preferably from 3 to 40 carbon atoms, or an alkoxycarbonylalkyl group having from 3 to 60, and more preferably from 3 to 40 carbon atoms.
Preferred examples of the alkyl group represented by R.
sup.
1 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a pentyl group, a hexyl group, a 2-ethylbutyl group, an isoheptyl group, an octyl group, a 2-ethylhexyl group, an isodecyl group, a dodecyl group, an isododecyl group, a tetradecyl group, a hexadecyl group, an isooctadecyl group, etc



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