6-Acylamino-penam-3-carboxylic and 7-acylamino-3-cephem-4-carboxylic acids |
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Dry pesticidal compositions |
| What is claimed is: 1. A dry pesticidal composition of a toxicant useful for crops having a melting ... |
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Amino acid solution for intravenous nutrition |
| OF THE PREFERRED EMBODIMENTS In the study leading to the present invention a rat whose small ... |
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Warm two tone flavored dentifrice |
| I claim: 1. An anhydrous heat releasing fluoride dentifrice which generates heat in the mouth ... |
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Toothpaste with zeolite polishing agent |
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Stabilized enzymatic dentifrice containing B-D-glucose and glucose oxidase |
| The enzymatic dentifrice of this invention comprises an enzyme system containing an oxidizable ... |
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Method and composition for prevention of plaque formation and plaque dependent diseases |
| I claim: 1. A method for preventing periodontitis in the oral cavity, said method comprising the ... |
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6-Aminopenicillanic acid sulfoxide silyl esters |
| I claim: 1. 6-aminopenicillanic acid sulfoxide silyl esters of the formula ##STR4## wherein R is ... |
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Cephalosporin esters |
| What I claim is: 1. A compound having the formula: ##STR12## , wherein A is phenylacetamido, ... |
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Process for the preparation of unsymmetrically 1,3-disubstituted nitroso ureas |
| What I claim is: 1. A compound of the formula: R--NH CO N (NO) CH.sub.2 --CH.sub.2 --Cl wherein (1) ... |
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Insecticidal heterocyclic compounds
| Details |
Inventors: Shiokawa, Kozo; Tsuboi, Shinichi; Moriya, Koichi; Hattori, Yumi; Honda, Ikuro; Shibuya, Katsuhiko;
Assignee: Nihon Bayer Agrochem K.K. (Tokyo, JP)
Primary Examiner: Morris; Patricia L.
Assistant Examiner:
Attorney, Agent or Firm: Sprung Kramer Schaeffer & Briscoe
Insecticidal heterocyclic compounds of the formula ##STR1## wherein A represents a five-membered or six-membered heteroaryl group containing one to three hetero atoms selected from the group consisting of S, O and N, said heteroaryl group being unsubstituted or substituted by a halogen atom or C.sub.1-4 alkyl group, Z represents a three-membered straight chain, each member being selected from the group consisting of CH.sub.2 --, O, S and N--R.sup.2 with at least one of said three members being O, S or N--R.sup.2, E represents CH.sub.2, O, S or N--R.sup.2, wherein R.sup.2 represents a hydrogen atom, a C.sub.1-4 alkyl group, a C.sub.1-4 alkoxy group or the group ##STR2## wherein R.sup.3 represents a hydrogen atom or halogen atom, X represents CH or N, Y represents a nitro group or cyano group, and R.sup.1 represents a hydrogen atom or methyl group. |
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DETAILED DESCRIPTION What is claimed is: 1. A heterocyclic compound of the formula: ##STR59## wherein A represents 2-chloropyridin-5-yl or 2-chlorothiazol-5-yl; Z. sup. 1 represents O; R. sup. 2 represents a hydrogen atom, a C. sub. 1-4 -alkyl group or 2-chloropyridin-5-ylmethyl; X represents CH or N; Y represents NO. sub. 2 or CN; and R. sup. 1 represents a hydrogen atom or a methyl group. 2. An insecticidal composition comprising an insecticidally effective amount of a compound according to claim 1 and a diluent. 3. A method of combating insects which comprises applying to such insects or to an insect habitat an insecticidally effective amount of a compound according to claim 1.
Description:
The present invention relates to novel heterocyclic compounds, to a process for their preparation, and to their use as insecticides. It has already been disclosed that 2-(nitromethylene) oxazolines have insecticidal activities (see ADVANCES IN PESTICIDE SCIENCE Part 2, pages 206 to 217. That article relates to symposia papers presented at the Fourth International Congress of Pesticide Chemistry, Zurich, Switzerland, Jul. 24-28, 1978, published by Pergamon Press). There have been found novel heterocyclic compounds of the formula (I), ##STR3## wherein A represents a five-membered or six-membered heteroaryl group comprising one to three hereto atoms selected from the group consisting of S, O and N, said heteroaryl group being unsubstituted or substituted by a halogen atom or C. sub. 1-4 alkyl group, Z represents a three-membered straight chain each member being selected from the group consisting of CH. sub. 2, O, S and N--R. sup. 2 with at least one of said three members being O, S or N--R. sup. 2, E represents CH. sub. 2, O, S or N--R. sup. 2, wherein R. sup. 2 represents a hydrogen atom, a C. sub. 1-4 alkyl group, a C. sub. 1-4 alkoxy group or the group ##STR4## wherein R. sup. 3 represents a or the group hydrogen atom or halogen atom, X represents CH or N, Y represents a nitro group or cyano group, and R. sup. 1 represents a hydrogen atom or methyl group
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