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 Optically active compound having a plurality of asymmetric carbon atoms

Details
Inventors: Ohno, Kouji; Saito, Shinichi; Inoue, Hiromichi; Miyazawa, Kazutoshi; Ushioda, Makoto;
Assignee: Chisso Corporation (Osaka, JP)
Primary Examiner: Maples; John S.
Assistant Examiner: Tucker; Philip
Attorney, Agent or Firm: Wenderoth, Lind & Ponack

An optically active compound having particularly a specific feature of increasing spontaneous polarization value as one of important specific features for ferroelectric liquid crystal compositions, and a ferroelectric liquid crystal composition containing the compound are provided, which compound is expressed by the formula ##STR1## wherein R.sup.1 represents a linear or branched chain alkyl, alkoxy, alkanoyl, alkoxycarbonyl or alkoxycarbonyloxy each of 1 -15C, H, halogen or -CN; R.sup.2 represents an optically active group having 2-20 skeletal atoms, ##STR2## wherein X represents H, halogen or -CN; l represents an integer of 1-10; m is 0 or 1; and * indicates asymmetric C.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS In the above formula (I), R.
sup.
1 is preferably a linear chain alkyl group or alkoxy group each of 4 to 14 carbon atoms.
Representative examples of the optically active group R.
sup.
2 are an optically active monohalogenated alkyl group or an alkyl group having an alkoxy branch each of 2 to 20 carbon atoms.
Examples of the monohalogenated alkyl group are ##STR5## In these formulas, X represents F, Cl or Br; and R.
sup.
3 represents a linear or branched chain alkyl group each of 1 to 15 carbon atoms and when R.
sup.
3 represents a branched chain alkyl group, it may be an optically active group.
Preferred examples of R.
sup.
2 wherein R.
sup.
3 represents a linear chain alkyl group and X represents a halogen atom are ##STR6## Further, preferred examples of R.
sup.
2 wherein R.
sup.
3 represents an optically active alkyl group and X represents a halogen atom are ##STR7## Further, preferred examples of R.
sup.
2 in the case of an alkyl group having an alkoxy branch are ##STR8## wherein R.
sup.
3 is as defined above and R.
sup.
4 represents a linear or branched chain alkyl group each of 1 to 10 carbon atoms and when R.
sup.
4 represents a branched chain alkyl group, R.
sup.
4 may be an optically active group.
Preferred examples of R.
sup.
2 wherein R.
sup.
3 and R.
sup.
4 are both a linear chain alkyl group are ##STR9## Preferred examples of R.
sup.
2 wherein R.
sup.
4 represents an optically active alkyl group are ##STR10## Preferred examples of R.
sup.
2 wherein R.
sup.
3 represents an optically active alkyl group and R.
sup.
4 represents a linear chain alkyl group are ##STR11## etc.
Preferred examples of R.
sup.
2 wherein R.
sup.
3 and R.
sup.
4 both represent an optically active alkyl group are ##STR12## Further, preferred examples of ##STR13## are ##STR14## Among these, more preferred examples are ##STR15## The specific feature of the compound expressed by the formula (I) of the present invention consists in that the compound has a large spontaneous polarization value (Ps) or potential spontaneous polarization value



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