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 Disazo compounds

Details
Inventors: Pesenacker, Manfred;
Assignee: Hoechst Aktiengesellschaft (Frankfurt, DE)
Primary Examiner: Higel; Floyd D.
Assistant Examiner:
Attorney, Agent or Firm: Curtis, Morris & Safford

Compounds of the general formula ##STR1## in which R.sup.1 and R.sup.2 are identical or different and denote hydrogen, chlorine or bromine, methyl, ethyl, methoxy, ethoxy or nitro and K denotes identical or different radicals of enolizable ketomethylene compounds which do not contain groups imparting solubility in water, are obtained by coupling one equivalent of the bisdiazonium compound obtained by bisdiazotizing the diamine of the formula ##STR2## in which R.sup.1 and R.sup.2 have the meaning mentioned above, with 2 equivalents of one or more compounds of the formula KH in which K has the meaning mentioned above. These disazo compounds are pigments which have a high tinctorial strength and good fastness to migration, light, heat and chemicals.

DETAILED DESCRIPTION I claim: 1.
A compound of the formula ##STR30## wherein one of the substituents X and Y means hydrogen, chlorine, methyl, methoxy or nitro, and the other means ##STR31## wherein Z is hydrogen, chlorine or methyl.
2.
The compound as claimed in claims 1, wherein Y is methyl and Z is hydrogen.
3.
The compound as claimed in claim 1, wherein X and Z are hydrogen.
4.
The compound as claimes in claim 1, wherein X is hydrogen and Z is 6-methyl.
5.
The compound as claimed in claim 1, wherein Y is chlorine and Z is hydrogen.
6.
The compound as claimed in claim 1, wherein Y is methoxy an Z is hydrogen.
7.
The compound as claimed in claim 1, wherein Y is methoxy and Z is 7-chlorine.




Description:
The invention relates to disazo compounds of the general formula I ##STR3## in which R.
sup.
1 and R.
sup.
2 can be identical or different and denote hydrogen, chlorine or bromine, methyl, ethyl, methoxy, ethoxy or nitro.
In the formula I, K denotes radicals of identical or different coupling components which do not contain groups imparting solubility in water.
K is, in particular, the radical of an enolizable ketomethylene compound, such as, for example, an acetoacetanilide or N-heterocyclic compound.
Preferred radicals K of this type correspond to the formulae II-VI, ##STR4## in which R is methyl or phenyl and Ar is a radical of the formula ##STR5## in which R.
sup.
3, R.
sup.
4 and R.
sup.
5, which are identical or not all the same, denote hydrogen, chlorine, bromine, lower alkyl, lower alkoxy, lower alkanoylamino, benzoylamino or nitro, or Ar is a radical from among those of the formulae (IIb)-(IIh) ##STR6## in which R.
sup.
6 is hydrogen, chlorine, bromine, lower alkyl, lower alkoxy, lower carboalkoxy or nitro, and R.
sup.
7 is the phenyl radical, which is optionally substituted by R.
sup.
6, or ##STR7## in which R.
sup.
8 denotes phenyl, tolyl or chlorophenyl and R.
sup.
9 denotes methyl, lower carboalkoxy, carbonamido or lower alkanoylamino; or ##STR8## in which Z represents oxygen, or sulfur,



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