Process for the preparation of extracts having high content in anthocyanosides

DETAILED DESCRIPTION We claim: 1.
A process for the preparation of an extract having high content of anthocyanosides which consists of: (a) reacting for 2-4 hours at room temperature an extract of fruits of Vaccinium muyrtillus, Ribes nigrum, Vitis vinifera or Sambucus nigra, containing 2-40% of anthocyanosides in addition to organic acids, salts, carbohydrates, flavonic glycosides, polyphenolic compounds and catechic tannins with 20-30 volumes of an aqueous solution containing at least 5 moles of bisulfite ion per mole of anthocyanosides to form a solution of an anthocyanoside-bisulfite adduct of pH 1-3.
5; (b) adjusting the pH of said solution from step a) to 5-6 by addition of 10% aqueous alkali and passing said solution through a column containing a resin obtained by polymerization of styrene, the amount of said resin being about 1 liter of resin per 10 grams of said flavonic glycosides and said catechic tannins to be absorbed, whereby said bisulfite adduct is eluted in the aqueous solution together with said salts, said organic acids and said carbohydrates while said polyphenolic compounds and said catechic tannins remain absorbed on said column; (c) acidifying to pH 1-2 said aqueous solution from step b) by addition of hydrochloric acid whereby the anthocyanoside-bisulfite adduct is cleaved, completing the cleavage by passing a stream of an inert gas in said aqueous solution, and extracting said aqueous solution with butanol or amyl alcohol whereby said anthocyanosides are obtained in a butanol or amyl alcohol solution, concentrating said butanol or amyl alcohol solution and recovering said extract of anthocyanosides therefrom.
2.
The process according to claim 1 wherein said extract of anthocyanosides is recovered from said butanol or amyl alcohol solution after concentration by lyophilization.
3.
The process according to claim 1 wherein said extract of anthocyanosides is recovered from said butanol or amyl alcohol solution after concentration by atomization.
4.
The process according to claim 1 wherein ethyl acetate is added to the butanol or amyl alcohol solution after concentration to precipitate said extract having a high content of anthocyanosides